Analysis of Compounds with Labile Hydrogens by HS/GC/MS
| Compound | Empty vial | 0.5 g Water | 0.5 g Stopper | 0.5 g PVC | ||||
|---|---|---|---|---|---|---|---|---|
| Concentration = SN 10 (µg/vial) | %RSD | Concentration = SN 10 (µg/g) | %RSD | Concentration = SN 10 (µg/g) | %RSD | Concentration = SN 10 (µg/g) | %RSD | |
| Butanoic acid | 0.5 | 18 | ND | NA | ND | NA | ND | NA |
| Hexanoic acid | 0.7 | 6 | ND | NA | ND | NA | ND | NA |
| Octanoic acid | >0.4 | 27 | ND | NA | ND | NA | ND | NA |
| Decanic acid | ND | NA | ND | NA | ND | NA | ND | NA |
| Dodecanoic acid | ND | NA | ND | NA | ND | NA | ND | NA |
| Tetradecanoic acid | ND | NA | ND | NA | ND | NA | ND | NA |
| 1-Butanol | 0.03 | 4 | 1.0 | 6 | 1.2 | 8 | 0.6 | 9 |
| 1-Hexanol | 0.03 | 4 | 1.0 | 6 | 0.6 | 3 | 1.4 | 9 |
| 1-Octanol | 0.03 | 2 | 1.2 | 2 | >0.2 | 6 | 6.2 | 25 |
| 1-Decanol | 0.03 | 11 | 2.2 | 20 | >1.0 | 25 | ND | NA |
| 1-Dodecanol | 0.04 | 34 | 2.2 | 13 | ND | NA | ND | NA |
| 1-Tetradecanol | 0.2 | 10 | 7.4 | 3 | ND | NA | ND | NA |
| 1-Butylamine | ND | NA | ND | NA | ND | NA | ND | NA |
| 1-Hexylamine | ND | NA | ND | NA | ND | NA | ND | NA |
| 1-Octylamine | ND | NA | ND | NA | ND | NA | ND | NA |
| 1-Decylamine | ND | NA | ND | NA | ND | NA | ND | NA |
| 1-Dodecylamine | ND | NA | ND | NA | ND | NA | ND | NA |
| 1-Tetradecylamine | ND | NA | ND | NA | ND | NA | ND | NA |
| Aniline | 0.02 | 3 | 0.2 | 24 | 0.4 | 12 | 3.6 | 2 |
| Dipropylamine | ND | NA | ND | NA | ND | NA | ND | NA |
| Dibutylamine | ND | NA | ND | NA | ND | NA | ND | NA |
| Dihexylamine | ND | NA | ND | NA | ND | NA | ND | NA |
| 2-Ethylhexanoic acid | >0.1 | 14 | ND | NA | 9.2 | 31 | ND | NA |
| Abietic acid | ND | NA | ND | NA | ND | NA | ND | NA |
| Tetrephthalic acid | ND | NA | ND | NA | ND | NA | ND | NA |
| Adipic acid | ND | NA | ND | NA | ND | NA | ND | NA |
| 3,5-DTBHA | ND | NA | ND | NA | ND | NA | ND | NA |
| Phenoxyethanol | 0.02 | 7 | ND | NA | 0.8 | 18 | ND | NA |
| Phenol | 0.02 | 5 | >0.2 | 13 | 0.4 | 8 | 6.2 | 19 |
| 1,3-Propanediol | ND | NA | ND | NA | ND | NA | ND | NA |
| 2-Ethyl-1-hexanol | 0.02 | 6 | 1.4 | 2 | 0.4 | 5 | ND | NA |
| Bisphenol A | ND | NA | ND | NA | ND | NA | ND | NA |
NA, not applicable; ND, not detected.