TABLE VIII

Levels of Extracted Elements, Polyethylene (PE)

Extraction DetailsAmount of Element Extracted, μg/g (ppm)5
SampleSolventVolume (mL)Temp. (°C)TimeWeight (g)AlBBaCaFeMgNaPSSiZn
1pH 2.52001211 h4.033.4333333333
Water2001211 h4.031.430.063333333
pH 9.52001211 h4.0333333NA6NA6333
2pH 2.5150554 days15.03331.03333333
pH 9.5150554 days15.03330.5033NA6NA60.103
32pH 32001211 h4.034.533.5334.0333.03
pH 92001211 h4.0333333NA6NA63.50.503
E/W200555 days4.034.533334.0336.03
4pH 2.5150554 days15.03333333330.303
pH 9.5150554 days15.0333333NA6NA60.201.23
5pH 3200556 months5.438.935633893345.23
pH 9200556 months5.43333.333NA6NA66.3403
E/W200556 months5.435.934.13310334.13
62pH 3150554 days16.330.9233330.92330.923
pH 9150554 days16.330.923333NA6NA630.923
E/W150554 days16.330.9233333330.923
  • Notes: 1The solvent types denoted with the pH were aqueous solutions prepared at that pH. Solvents at pH 3 and below were KCl/HCl mixtures. Solvents at pH above 3 were dilute phosphate buffers. W = purified water. E/W = 40/60 (v/v) ethanol/water.

  • 2 This material was gamma-irradiated.

  • 3 — = not present in the sample in reportable quantities.

  • 4PE housing with silicone rubber gasket.

  • 5 Elements that were not present in the extracts at reportable levels, in addition to those listed in this table, included Ag, As, Be, Bi, Cd, Co, Cr, Cu, Ge, Li, Mo, Mn, Ni, Pb, Sb, Se, Sn, Sr, Ti, V, and Zr.

  • 6 NA = not applicable. As Na and P were components of the buffer used in these solvents, extractable quantities of these elements could not be ascertained.