Table IX

Extracted Elemental Impurities Reported for Polymethylmethacrylate (PMMA)

ElementConcentration (mg/kg unless noted)Extraction DetailsCommentsRef.
SolventConditions
AlNR1, 0.30Low pH (≈3)Sealed vessel, 55 °C for 4 days, 0.1 g sample/mL solvent2 materials tested; resins, parts312
NRHigh pH (≈9)
NR, 1.5Ethanol/water
BNR–0.39Low pH (≈3)
NRHigh pH (≈9)
0.40, 0.69Ethanol/water
Ca0.60, 1.2Low pH (≈3)
NR, 0.99High pH (≈9)
NR, 2.6Ethanol/water
Mg0.0013% acetic acidSealed vessel, 40 °C for 10 days, 0.15 g sample/mL solventTotal pool = 5.2 mg/kg21
NaNR, 0.49Low pH (≈3)Sealed vessel, 55 °C for 4 days, 0.1 g sample/mL solvent2 materials tested; resins, parts312
NA2High pH (≈9)
NR, 8.9Ethanol/water
PNRLow pH (≈3)
NAHigh pH (≈9)
NR, 1.8Ethanol/water
SNR, 0.59Low pH (≈3)
NR, 2.0High pH (≈9)
NR, 23Ethanol/water
Si0.89, 2.6Low pH (≈3)
0.30, 18High pH (≈9)
1.9, 40Ethanol/water
Zn0.0043% acetic acidSealed vessel, 40 °C for 10 days, 0.15 g sample/mL solventTotal pool = <1 mg/kg21
  • Notes:

  • 1 NR = Not reported: not extracted at reportable levels (generally less than 0.01 μg/g).

  • 2 NA = Not applicable; element was a component of the extracting solvent.

  • 3 Elements that were not extracted in reportable levels included Ag, As, Ba, Be, Bi, Cd, Co, Cr, Cu, Fe, Ge, Li, Mn, Mo, Ni, Pb, Sb, Se, Sn, Sr, Ti, V, and Zr.