Table V

Extracted Elemental Impurities Reported for Polycarbonate (PC)

ElementConcentration (mg/kg unless noted)Extraction DetailsCommentsRef.
SolventConditions
AlNR1Low pH (≈3)Sealed vessel, 55 °C for 4 days, 0.1–0.3 g sample/mL solvent6 materials tested; resins and parts312
NR–0.50High pH (≈9)
NREthanol/water
BNR–0.40Low pH (≈3)Sealed vessel, 55 °C for 4 days, 0.1–0.3 g sample/mL solvent6 materials tested; resins and parts312
NR–0.50High pH (≈9)
NR–0.80Ethanol/water
0.4 ng/mLWaterDynamic extraction with recirculation, ambient temperature, 24 hIntact part (connector)18
<0.1 ng/mLEthanol
Br1.1pH 2.5Sealed vessel, 121 °C for 1 h, 0.025 g sample/mL solventMolded part435
0.07pH 9.5
CaNR–0.15Low pH (≈3)Sealed vessel, 55 °C for 4 days, 0.1–0.3 g sample/mL solvent6 materials tested; resins and parts312
NR–0.78High pH (≈9)
NR–0.03Ethanol/water
<0.1 ng/mLWaterDynamic extraction with recirculation, ambient temperature, 24 hIntact part (connector)18
1 ng/mLEthanol
6.6pH 2.5Sealed vessel, 121 °C for 1 h, 0.025 g sample/mL solventMolded part435
0.8pH 9.5
Cr0.07pH 2.5Sealed vessel, 121 °C for 1 h, 0.025 g sample/mL solventMolded part435
0.02pH 9.5
FeNR–0.14Low pH (≈3)Sealed vessel, 55 °C for 4 days, 0.1–0.3 g sample/mL solvent6 materials tested; resins and parts312
NRHigh pH (≈9)
NREthanol/waterSealed vessel, 121 °C for 1 h, 0.025 g sample/mL solventMolded part435
0.71pH 2.5
0.06pH 9.5
MgNRLow pH (≈3)Sealed vessel, 55 °C for 4 days, 0.1–0.3 g sample/mL solvent6 materials tested; resins and parts312
NRHigh pH (≈9)
NREthanol/waterSealed vessel, 121 °C for 1 h, 0.025 g sample/mL solventMolded part435
0.24pH 2.5
0.17pH 9.5
NaNR–0.30Low pH (≈3)Sealed vessel, 55 °C for 4 days, 0.1–0.3 g sample/mL solvent6 materials tested; resins and parts312
NA2High pH (≈9)
NR–0.58Ethanol/waterDynamic extraction with recirculation, ambient temperature, 24 hIntact part (connector)18
0.2 ng/mLWaterSealed vessel, 121 °C for 1 h, 0.025 g sample/mL solventMolded part435
<0.1 ng/mLEthanol
1.0pH 2.5
PNRLow pH (≈3)Sealed vessel, 55 °C for 4 days, 0.1–0.3 g sample/mL solvent6 materials tested; resins and parts312
NAHigh pH (≈9)
NREthanol/water
SNR–0.48Low pH (≈3)Sealed vessel, 55 °C for 4 days, 0.1–0.3 g sample/mL solvent6 materials tested, resins and parts312
NR–0.48High pH (≈9)
NREthanol/water
SiNR–51Low pH (≈3)Sealed vessel, 55 °C for 4 days, 0.1–0.3 g sample/mL solvent6 materials tested; resins and parts312
NR–50High pH (≈9)
NR–57Ethanol/water
ZnNRLow pH (≈3)Sealed vessel, 55 °C for 4 days, 0.1–0.3 g sample/mL solvent6 materials tested; resins and parts312
NRHigh pH (≈9)
NREthanol/waterDynamic extraction with recirculation, ambient temperature, 24 hIntact part (connector)18
0.5 ng/mLWater
<0.1 ng/mLEthanolSealed vessel, 121 °C for 1 h, 0.025 g sample/mL solventMolded part435
0.12pH 2.5
0.03pH 9.5
  • Notes:

  • 1 NR = Not reported: not extracted at reportable levels (generally less than 0.01 μg/g).

  • 2 NA = Not applicable; element was a component of the extracting solvent.

  • 3 Elements that were not extracted in reportable levels included Ag, Ba, As, Be, Bi, Cd, Co, Cr, Cu, Ge, Li, Mn, Mo, Ni, Pb, Sb, Se, Sn, Sr, Ti, V, and Zr.

  • 4 Elements that were not extracted in reportable levels (<0.01 μg/g) included Al, As. Co, Cu, K, Mo, Ni, Pb, Si, Sb, Sr, Ti, and V.